Morphology and Properties of Mg2Si Phase Modified by Pb in As-Cast Mg-2.5Si-xPb Alloys

• Published in: Materials Vol. 17; no. 8; p. 1811
• Main Authors: Chen, Liang, Yang, Wenpeng, Cui, Hongbao, Wang, Ying, Xu, Zhichao
• Format: Journal Article
• Language: English
• Published: Basel MDPI AG 01.04.2024
• Subjects: Adsorption; Atoms & subatomic particles; Crystal structure; Energy; First principles; first-principles calculation; Hardness; Intermetallic compounds; Lead; Magnesium alloys; Magnesium compounds; Mechanical properties; Metal silicides; Mg2(SixPb1−x) phases; Mg2Si; modification; Morphology; Nanoindentation; Solid solutions; Solidification; United States > US; Japan
• ISSN: 1996-1944; 1996-1944
• DOI: 10.3390/ma17081811

Pb plays an important role in determining the morphologies and mechanical properties of the Mg2Si phase in Mg-2.5Si-xPb alloys. As the amount of Pb increases from 0.4 wt.% to 1 wt.%, the primary Mg2Si phase is refined during solidification. Its morphologies transform from equiaxed-dendrite to polygonal and finally to roughly circular. The key reason for morphology evolution is the preferential adsorption of Pb atoms on Mg2Si {100} surfaces to suppress the growth rate along the ⟨100⟩ directions, which is demonstrated by the adsorption model based on first principles. In addition, the hardness of the Mg2Si phase decreases with the increasing solution content of Pb according to the results of the nanoindentation. With the addition of Pb at 1 wt.%, Pb content in the primary Mg2Si phase reaches a maximum of 0.4 wt.%, and the hardness of the primary Mg2Si phase reaches a minimum of 3.64 GPa. This reduction in hardness is attributed to the augmented ionic bond ratio resulting from the solution of Pb, which concurrently enhances the toughness of the Mg2Si phase.