Functional microporous materials of metal carboxylate: Gas-occlusion properties and catalytic activities

Copper(II) terephthalate is the first transition metal complex found capable of adsorbing gases. This complex has opened the new field of adsorbent complex chemistry. It is recognized as the lead complex in the construction of microporous complexes. This specific system has been expanded to a system...

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Bibliographic Details
Published inJournal of solid state chemistry Vol. 178; no. 8; pp. 2555 - 2573
Main Authors Mori, Wasuke, Sato, Tomohiko, Ohmura, Tesushi, Nozaki Kato, Chika, Takei, Tohru
Format Journal Article
LanguageEnglish
Published United States Elsevier Inc 01.08.2005
Subjects
ADSORBENTS
COPPER COMPLEXES
Gas-occlusion properties
GASES
HYDROGEN
Hydrogen exchange reactions
INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY
Metalloporphyrin
Microporous material
MOLYBDENUM COMPLEXES
Olefin hydrogenation
POLYMERS
RHODIUM COMPLEXES
RUTHENIUM COMPLEXES
Self-assembly
Transition metal carboxylate polymer complex
Self-assembly
Microporous material
Olefin hydrogenation
Gas-occlusion properties
Transition metal carboxylate polymer complex
Metalloporphyrin
Hydrogen exchange reactions
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Summary:Copper(II) terephthalate is the first transition metal complex found capable of adsorbing gases. This complex has opened the new field of adsorbent complex chemistry. It is recognized as the lead complex in the construction of microporous complexes. This specific system has been expanded to a systematic series of derivatives of other isomorphous transition metals, molybdenum(II), ruthenium(II, III), and rhodium(II). These complexes with open frameworks are widely recognized as very useful materials for applications to catalysis, separation at molecular level, and gas storage. Novel microporous intramolecular reaction systems.
ISSN:0022-4596
1095-726X
DOI:10.1016/j.jssc.2005.07.009