Raman spectral analysis of liquid ammonia and aqueous solution of ammonia
The intramolecular vibrational region of the Raman spectra of liquid ammonia and aqueous solution of ammonia was studied. We propose an interpretation of these spectra assuming the dynamic structures made by hydrogen bonds. The normal mode wavenumbers of ammonia monomer, ammonia dimer and ammonia–wa...
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| Published in | Journal of Raman spectroscopy Vol. 33; no. 6; pp. 485 - 493 |
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| Main Authors | , |
| Format | Journal Article |
| Language | English |
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Chichester, UK
John Wiley & Sons, Ltd
01.06.2002
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| Abstract | The intramolecular vibrational region of the Raman spectra of liquid ammonia and aqueous solution of ammonia was studied. We propose an interpretation of these spectra assuming the dynamic structures made by hydrogen bonds. The normal mode wavenumbers of ammonia monomer, ammonia dimer and ammonia–water complex were calculated by the GF matrix method. These wavenumbers almost fit the spectral peaks. For liquid ND3 and ND3–D2O solution, the spectra are also explained in the same way. Copyright © 2002 John Wiley & Sons, Ltd. |
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| AbstractList | Abstract
The intramolecular vibrational region of the Raman spectra of liquid ammonia and aqueous solution of ammonia was studied. We propose an interpretation of these spectra assuming the dynamic structures made by hydrogen bonds. The normal mode wavenumbers of ammonia monomer, ammonia dimer and ammonia–water complex were calculated by the GF matrix method. These wavenumbers almost fit the spectral peaks. For liquid ND
3
and ND
3
–D
2
O solution, the spectra are also explained in the same way. Copyright © 2002 John Wiley & Sons, Ltd. The intramolecular vibrational region of the Raman spectra of liquid ammonia and aqueous solution of ammonia was studied. We propose an interpretation of these spectra assuming the dynamic structures made by hydrogen bonds. The normal mode wavenumbers of ammonia monomer, ammonia dimer and ammonia–water complex were calculated by the GF matrix method. These wavenumbers almost fit the spectral peaks. For liquid ND3 and ND3–D2O solution, the spectra are also explained in the same way. Copyright © 2002 John Wiley & Sons, Ltd. The intramolecular vibrational region of the Raman spectra of liquid ammonia and aqueous solution of ammonia was studied. We propose an interpretation of these spectra assuming the dynamic structures made by hydrogen bonds. The normal mode wavenumbers of ammonia monomer, ammonia dimer and ammonia-water complex were calculated by the GF matrix method. These wavenumbers almost fit the spectral peaks. For liquid ND3 and ND3-D2O solution, the spectra are also explained in the same way. |
| Author | Tominaga, Yasunori Ujike, Tomoko |
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| Cites_doi | 10.1139/p54-069 10.1021/j100593a032 10.1021/bk-1996-0629.ch009 10.1021/j100488a017 10.1063/1.1365096 10.1016/0584-8539(91)80126-4 10.1021/j100160a017 10.1063/1.1365097 10.1021/ja00749a002 10.1021/j100637a006 10.1063/1.1679868 10.1063/1.453681 10.1016/0022-2860(90)80127-6 10.1016/0022-2852(66)90231-1 10.1063/1.469016 10.1119/1.1934101 10.1139/v91-096 |
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