Raman spectral analysis of liquid ammonia and aqueous solution of ammonia
The intramolecular vibrational region of the Raman spectra of liquid ammonia and aqueous solution of ammonia was studied. We propose an interpretation of these spectra assuming the dynamic structures made by hydrogen bonds. The normal mode wavenumbers of ammonia monomer, ammonia dimer and ammonia–wa...
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| Published in | Journal of Raman spectroscopy Vol. 33; no. 6; pp. 485 - 493 |
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| Main Authors | , |
| Format | Journal Article |
| Language | English |
| Published |
Chichester, UK
John Wiley & Sons, Ltd
01.06.2002
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| Online Access | Get full text |
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| Summary: | The intramolecular vibrational region of the Raman spectra of liquid ammonia and aqueous solution of ammonia was studied. We propose an interpretation of these spectra assuming the dynamic structures made by hydrogen bonds. The normal mode wavenumbers of ammonia monomer, ammonia dimer and ammonia–water complex were calculated by the GF matrix method. These wavenumbers almost fit the spectral peaks. For liquid ND3 and ND3–D2O solution, the spectra are also explained in the same way. Copyright © 2002 John Wiley & Sons, Ltd. |
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| Bibliography: | Ministry of Education, Science, Culture, and Sports. istex:57FD5E70550C63D306823A708E1B10253F051E02 ark:/67375/WNG-71GWPJ8X-D ArticleID:JRS881 ObjectType-Article-2 SourceType-Scholarly Journals-1 ObjectType-Feature-1 content type line 23 |
| ISSN: | 0377-0486 1097-4555 |
| DOI: | 10.1002/jrs.881 |