Slightly broken icosahedral symmetry advances Thomson problem

• Published in: Physics letters. A Vol. 379; no. 4; pp. 372 - 376
• Main Authors: Roshal, D.S., Myasnikova, A.E., Rochal, S.B.
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 06.02.2015
• Subjects: Caspar and Klug theory; Crystal defects; Crystal structure; Crystals; Distortion; Elongated structure; Flattening; Icosahedral phase; Scars; Self-assembly; Solid state physics; Spherical crystals; Thomson problem; Topological defects; Viral capsids; Viral capsids; Self-assembly; Thomson problem; Topological defects; Spherical crystals; Caspar and Klug theory
• ISSN: 0375-9601; 1873-2429
• DOI: 10.1016/j.physleta.2014.11.039

To advance Thomson problem we generalize physical principles suggested by Caspar and Klug (CK) to model icosahedral capsids. Proposed simplest distortions of the CK spherical arrangements yield new-type trial structures very close to the lowest energy ones. In the region 600≤N≤1000, where N is the number of particles in the structure, we found 40 new spherical crystals with the lowest ever seen energies and curvature-induced topological defects being not the well-known elongated scars but flatten pentagons. These crystals have N values prohibited in the CK model and demonstrate a new way to combine the local hexagonal order and spherical geometry. •We break the icosahedral symmetry of Caspar and Klug model of viral capsids.•Simplest distortion of global icosahedral arrangement in 2D nanocrystals is found.•Trial 2D spherical structures obtained are close to the lowest energy Thomson ones.•A new way to combine the local hexagonal order and spherical geometry is proposed.•List of Thomson structures with the lowest seen energies is essentially updated.