Non-linear optical crystals of 2,2,3-trimethyl-3-(1 H-1,2,3,4-tetrazol-5-yl)-butanenitrile

The title compound, C(8)H(13)N(5), is a novel functionally substituted 5-alkyltetrazole. The substituent on the tetrazole C atom is symmetrical, with intrinsic symmetry close to m. There is intermolecular N-H.N hydrogen bonding between adjacent tetrazole rings, which is responsible for the formation...

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Published inActa crystallographica. Section C, Crystal structure communications Vol. 59; no. Pt 7; pp. o388 - o389
Main Authors LYAKHOV, Alexander S, VOITEKHOVICH, Sergey V, GAPONIK, Pavel N, IVASHKEVICH, Ludmila S
Format Journal Article
LanguageEnglish
Published Oxford Blackwell 01.07.2003
Subjects
Condensed matter: structure, mechanical and thermal properties
Exact sciences and technology
Fundamental areas of phenomenology (including applications)
Heterocyclic compounds
Nonlinear optical crystals
Optical materials
Optics
Organic compounds
Physics
Structure of solids and liquids; crystallography
Structure of specific crystalline solids
Five membered ring
Hydrogen bonds
Molecular structure
Nitrogen heterocycle
Nitriles
Optical materials
XRD
Experimental study
Nonlinear optics
Organic compounds
Crystal structure
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Summary:The title compound, C(8)H(13)N(5), is a novel functionally substituted 5-alkyltetrazole. The substituent on the tetrazole C atom is symmetrical, with intrinsic symmetry close to m. There is intermolecular N-H.N hydrogen bonding between adjacent tetrazole rings, which is responsible for the formation of one-dimensional polymeric chains running along the c axis. The polycrystalline compound exhibits frequency doubling for incident light (lambda = 1064 nm) from a YAG:Nd pulsed laser.
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ISSN:0108-2701
1600-5759
DOI:10.1107/s0108270103011387