Yttrium(III)-Catalyzed Intramolecular Alkyne Hydroaminations

The neutral Y(III) complex 4 has been shown to be an effective precatalyst for intramolecular alkyne hydroaminations that provide cyclic amines in good to excellent yields.

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Bibliographic Details
Published inAdvanced synthesis & catalysis Vol. 348; no. 6; pp. 701 - 704
Main Authors Kim, Hyunseok, Livinghouse, Tom, Shim, Jun Hwan, Lee, Seong Guk, Lee, Phil Ho
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 01.04.2006
WILEY‐VCH Verlag
Wiley
Subjects
alkynes
catalysis
Chemistry
Chemistry, Applied
Chemistry, Organic
cyclization
hydroamination
Physical Sciences
Science & Technology
yttrium
SCOPE
ALKENE HYDROAMINATION
alkynes
catalysis
ORGANOLANTHANIDE-CATALYZED HYDROAMINATION
BOND FORMATION
UNPROTECTED AMINO OLEFINS
cyclization
hydroamination
yttrium
AMIDO COMPLEXES
GROUP-3 METALS
INTERMOLECULAR HYDROAMINATION
REGIOSPECIFIC CYCLIZATION
METAL-COMPLEXES
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Summary:The neutral Y(III) complex 4 has been shown to be an effective precatalyst for intramolecular alkyne hydroaminations that provide cyclic amines in good to excellent yields.
Bibliography:ark:/67375/WNG-RNZ36PF5-H
istex:6055EBF4445828EBEA08E54DE6FE24E696849C11
ArticleID:ADSC200505448
ISSN:1615-4150
1615-4169
DOI:10.1002/adsc.200505448