Supramolecular Click Assembly of a Fused Double-Stranded [MnII3] Dihelicate

A trinuclear MnII complex was obtained by reaction of manganese(II) perchlorate with the ligand 2‐methoxy‐6‐(pyridine‐2‐ylhydrazonomethyl)phenol in methanol. The X‐ray crystal structure of [Mn3L4](ClO4)2(H2O)2 (1) reveals that the “bent” chain of the MnII ions is assembled by a unique click‐assembly...

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Published inEuropean Journal of Inorganic Chemistry Vol. 2007; no. 26; pp. 4119 - 4122
Main Authors Tang, Jinkui, Costa, José Sánchez, Aromí, Guillem, Mutikainen, Ilpo, Turpeinen, Urho, Gamez, Patrick, Reedijk, Jan
Format Book Review Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 01.09.2007
WILEY‐VCH Verlag
Subjects
Click chemistry
Ferromagnetic interactions
Helicates
Manganese
Self-assembly
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Summary:A trinuclear MnII complex was obtained by reaction of manganese(II) perchlorate with the ligand 2‐methoxy‐6‐(pyridine‐2‐ylhydrazonomethyl)phenol in methanol. The X‐ray crystal structure of [Mn3L4](ClO4)2(H2O)2 (1) reveals that the “bent” chain of the MnII ions is assembled by a unique click‐assembly of two double‐stranded helicates. Magnetic susceptibility measurements show weak ferromagnetic interactions between the metal ions. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)
Bibliography:FP6 Network of Excellence "Magmanet" - No. 515767
Leiden University Study Group Werkgroep Fundamenteel Materialen-Onderzoek (WFMO)
European Cooperation in the Field of Science and Technology (COST) - No. Action D35/0011
istex:D0061828A93929887058A8E4084775DE24984AD7
ArticleID:EJIC200700697
ark:/67375/WNG-WH0MNJCS-N
ISSN:1434-1948
1099-0682
DOI:10.1002/ejic.200700697