Synthesis, Crystal Structure and Luminescence of [Ag(PPh3)2(H2TMT)]

The silver complex Ag(PPh3)2(H2TMT) (1)(H3TMT = 2,4,6‐trimercapto‐1,3,5‐triazine) has been synthesized and characterized. The ligand trimercaptotriazine exhibits a novel coordination mode and the complex shows a special hydrogen bonding linkage in the crystal packing. The colorless crystals of 1 exh...

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Bibliographic Details
Published inZeitschrift für anorganische und allgemeine Chemie (1950) Vol. 631; no. 8; pp. 1532 - 1535
Main Authors Wei, Yong-Qin, Wu, Ke-Chen, Zhuang, Bo-Tao, Zhou, Zhang-Feng, Zhang, Ming-Xin, Liu, Cai-Ping
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 01.06.2005
WILEY‐VCH Verlag
Subjects
Crystal structure
Luminescence spectra
Silver
Trimercaptotriazine
π-π imteraction
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Summary:The silver complex Ag(PPh3)2(H2TMT) (1)(H3TMT = 2,4,6‐trimercapto‐1,3,5‐triazine) has been synthesized and characterized. The ligand trimercaptotriazine exhibits a novel coordination mode and the complex shows a special hydrogen bonding linkage in the crystal packing. The colorless crystals of 1 exhibit broad emission in the visible region at room temperature. TDDFT calculation indicated that the π–π attraction is crucial for fluorescence of the title complex.
Bibliography:istex:152B6528E25BB41A3A1DB8963AA75F35D19C7355
ArticleID:ZAAC200400524
ark:/67375/WNG-3D645H44-J
ISSN:0044-2313
1521-3749
DOI:10.1002/zaac.200400524