Formation of Hexagonal Coordination Complexes

The synthesis of the ligand 1,3‐bis(3′‐pyridylethynyl)benzene and the coordination complex formed with copper(II) acetate is described. The complex is hexagonal with two ligands bridged by paddlewheel‐shaped dimeric copper(II) acetate moieties. The complexes are packed in such a way that the benzene...

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Published inEuropean journal of inorganic chemistry Vol. 2005; no. 1; pp. 45 - 46
Main Authors Schultheiss, Nate, Ellsworth, Joseph M., Bosch, Eric, Barnes, Charles L.
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 01.01.2005
WILEY‐VCH Verlag
Subjects
Crystal engineering
Metallacycles
Microporous materials
N ligands
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Summary:The synthesis of the ligand 1,3‐bis(3′‐pyridylethynyl)benzene and the coordination complex formed with copper(II) acetate is described. The complex is hexagonal with two ligands bridged by paddlewheel‐shaped dimeric copper(II) acetate moieties. The complexes are packed in such a way that the benzene rings from two separate complexes penetrate into the central cavity. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)
Bibliography:istex:9EEB0AFFB9C43777A2974D54EA34B806D1E7A002
ark:/67375/WNG-K87MQ4T1-W
ArticleID:EJIC200400722
ISSN:1434-1948
1099-0682
DOI:10.1002/ejic.200400722