Enantioselective Synthesis of Thiosulfinates and of Acyclic Alkylidenemethylene Sulfide Sulfoxides

Enantioselectivities up to 75 % have been found in the catalytic mono‐oxidation of di‐tert‐butyl disulfide and related compounds as well as of ketene‐S,S‐acetals with an in situ generated chiral dioxirane. The effect of solvents on the enantiomeric excess has also been examined. (© Wiley‐VCH Verlag...

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Bibliographic Details
Published inEuropean Journal of Organic Chemistry Vol. 2005; no. 9; pp. 1727 - 1730
Main Authors Colonna, Stefano, Pironti, Vincenza, Drabowicz, Jozef, Brebion, Franck, Fensterbank, Louis, Malacria, Max
Format Book Review Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 01.05.2005
WILEY‐VCH Verlag
Wiley
Subjects
Asymmetric synthesis
Bovine serum albumin
Chemistry
Chemistry, Organic
Chiral dioxirane
Enantioselectivity
Physical Sciences
Science & Technology
Thiosulfinate
enantioselectivity
OXIDATION
ASYMMETRIC-SYNTHESIS
BIS(SULFOXIDES)
EPOXIDATION
ACID-DERIVATIVES
TERT-BUTANESULFINYL IMINES
asymmetric synthesis
AMINES
thiosulfinate
chiral dioxirane
bovine serum albumin
BOVINE SERUM-ALBUMIN
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Summary:Enantioselectivities up to 75 % have been found in the catalytic mono‐oxidation of di‐tert‐butyl disulfide and related compounds as well as of ketene‐S,S‐acetals with an in situ generated chiral dioxirane. The effect of solvents on the enantiomeric excess has also been examined. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)
Bibliography:istex:B3C7CFA41768BD276B33C5B1078ABDCD378904F5
ark:/67375/WNG-3M9TJ83S-1
ArticleID:EJOC200400892
ISSN:1434-193X
1099-0690
DOI:10.1002/ejoc.200400892