A Supramolecular Approach to Organic Alloys: Cocrystals and Three- and Four-Component Solid Solutions of 1,4-Diazabicyclo[2.2.2]octane and 4-X-Phenols (X=Cl, CH3, Br)

• Published in: Angewandte Chemie International Edition Vol. 46; no. 22; pp. 4132 - 4135
• Main Authors: Dabros, Marta, Emery, Paul R., Thalladi, Venkat R.
• Format: Journal Article
• Language: English
• Published: Weinheim WILEY-VCH Verlag 25.05.2007; WILEY‐VCH Verlag
• Subjects: crystal engineering; organic alloys; phenols; solid solutions; supramolecular chemistry

Triple play: The crystallization of 1,4‐diazabicyclo[2.2.2]octane (A) with one, two, or three different 4‐substituted phenols (B, C, D) leads to cocrystals (for example, AB2, left) or solid solutions (for example, A(B,C,D)2, right). The repeat units of these multicomponent organic solids are supramo...