A Supramolecular Approach to Organic Alloys: Cocrystals and Three- and Four-Component Solid Solutions of 1,4-Diazabicyclo[2.2.2]octane and 4-X-Phenols (X=Cl, CH3, Br)

Triple play: The crystallization of 1,4‐diazabicyclo[2.2.2]octane (A) with one, two, or three different 4‐substituted phenols (B, C, D) leads to cocrystals (for example, AB2, left) or solid solutions (for example, A(B,C,D)2, right). The repeat units of these multicomponent organic solids are supramo...

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Bibliographic Details
Published inAngewandte Chemie International Edition Vol. 46; no. 22; pp. 4132 - 4135
Main Authors Dabros, Marta, Emery, Paul R., Thalladi, Venkat R.
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 25.05.2007
WILEY‐VCH Verlag
Subjects
crystal engineering
organic alloys
phenols
solid solutions
supramolecular chemistry
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Summary:Triple play: The crystallization of 1,4‐diazabicyclo[2.2.2]octane (A) with one, two, or three different 4‐substituted phenols (B, C, D) leads to cocrystals (for example, AB2, left) or solid solutions (for example, A(B,C,D)2, right). The repeat units of these multicomponent organic solids are supramolecular assemblies of three molecules.
Bibliography:istex:1CBE50BCC36E61EE310B8664A8BF62A6FED42BEE
ark:/67375/WNG-43JHW8QQ-R
ArticleID:ANIE200604830
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200604830