Preparation and X-ray Structures of trans-5,6-Diaryl-5,6-dihydro-1,10-phenanthroline-5,6-diols: Formation of Supramolecular Rod by Hydrogen Bonds

A series of X-ray analyses on the newly prepared title molecules have revealed that the one-dimensional rod-like structures are commonly present in the crystals of trans-dihydrophenan-throlinediols. The architecture is of interest from the viewpoint of supramolecular chirality because homochiral dio...

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Bibliographic Details
Published inChemistry letters Vol. 38; no. 7; pp. 670 - 671
Main Authors Suzuki, Takanori, Miura, Youhei, Tamaki, Ryuuichi, Kawai, Hidetoshi, Fujiwara, Kenshu
Format Journal Article
LanguageEnglish
Published TOKYO Chemical Soc Japan 05.07.2009
Subjects
Chemistry
Chemistry, Multidisciplinary
Physical Sciences
Science & Technology
SYSTEMS
TRANSMISSION
HELICITY
1,10-PHENANTHROLINE-5,6-QUINONE
AMPLIFICATION
POINT CHIRALITY
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Summary:A series of X-ray analyses on the newly prepared title molecules have revealed that the one-dimensional rod-like structures are commonly present in the crystals of trans-dihydrophenan-throlinediols. The architecture is of interest from the viewpoint of supramolecular chirality because homochiral diol molecules with the same sense of helicity are connected in a head-to-tail fashion by a pair of N center dot center dot center dot H-O hydrogen bonds.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.2009.670