The bitumen microstructure: a fluorescent approach

Five bituminous samples were carefully studied by confocal laser scanning microscopy using 488 nm excitation radiation and observing 500–530 nm of emission. The images revealed the microstructure of bitumen. The influence of the admixture of mineral aggregates concerning the microstructure was teste...

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Bibliographic Details
Published inMaterials and structures Vol. 49; no. 1-2; pp. 167 - 180
Main Authors Handle, Florian, Füssl, Josef, Neudl, Susanna, Grossegger, Daniel, Eberhardsteiner, Lukas, Hofko, Bernhard, Hospodka, Markus, Blab, Ronald, Grothe, Hinrich
Format Journal Article
LanguageEnglish
Published Dordrecht Springer Netherlands 2016
Springer Nature B.V
Subjects
Asphaltenes
Bitumens
Building construction
Building Materials
Civil Engineering
Emission analysis
Emission spectroscopy
Engineering
Fluorescence
Machines
Maltenes
Manufacturing
Materials Science
Microstructure
Original Article
Origins
Processes
Solid Mechanics
Theoretical and Applied Mechanics
Optical microscopy
Microstructure
Photoluminescence spectroscopy
Bitumen
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Summary:Five bituminous samples were carefully studied by confocal laser scanning microscopy using 488 nm excitation radiation and observing 500–530 nm of emission. The images revealed the microstructure of bitumen. The influence of the admixture of mineral aggregates concerning the microstructure was tested. For the minerals, no significant influence was found. For understanding the origin of fluorescent signals, the samples were separated into asphaltenes and maltenes and analyzed with fluorescence spectroscopy. Although former works have assumed the origin of fluorescent emissions in bitumen to be found in the asphaltene fraction, the asphaltenes produce little to no emissions, but the maltenes exhibit strong fluorescence in the observed spectral region. For deeper insight, fractionation of the bitumina into the SARA fractions by chromatographic column separation was necessary. The fluorescence spectra of these fractions were analyzed and revealed the aromatics and resin phases to be the only components capable of sufficiently intense fluorescent emission. This is a strong argument for a complex internal microstructure consisting of a mantle of aromatics surrounding an inner core.
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ISSN:1359-5997
1871-6873
DOI:10.1617/s11527-014-0484-3