Electrodeposited Palladium Nanoflowers for Electrocatalytic Applications

• Published in: Fuel cells (Weinheim an der Bergstrasse, Germany) Vol. 13; no. 6; pp. 1196 - 1204
• Main Authors: Maniam, K. K., Chetty, R.
• Format: Journal Article
• Language: English
• Published: Weinheim WILEY-VCH Verlag 01.12.2013; WILEY‐VCH Verlag; Wiley Subscription Services, Inc
• Subjects: Electrocatalysis; Electrodeposition; Formic Acid Oxidation; Fuel Cells; Nanomaterials; Oxygen Reduction Reaction; Palladium; Polyethylene Glycol
• ISSN: 1615-6846; 1615-6854
• DOI: 10.1002/fuce.201200162

Palladium was electrodeposited on an electrochemically activated carbon black substrate using potentiostatic technique, with and without the addition of polyethylene glycol (PEG‐6000) as an additive. Scanning electron micrographs showed change in morphology of Pd from spherical to flower, with increasing additive concentration. As an electrocatalyst for oxygen reduction reaction (ORR), formic acid oxidation and CO stripping, Pd nanoflowers displayed three‐ to fourfold increase in electrocatalytic activity in comparison to the spherical Pd deposits in terms of electrochemical surface area (ESA) and mass specific current density. X‐ray diffraction (XRD) patterns showed, the introduction of additive with varying concentration effect the direction of Pd growth thereby changing the morphology from spherical to flower. The result demonstrates an increase in efficiency of Pd utilization achieved with the addition of PEG during electrodeposition, which could also be applicable to other precious metal electrocatalysts. A scheme for the change in Pd morphology during electrodeposition with additive is also proposed.