Structural evolution in the isothermal crystallization process of the molten nylon 10/10 traced by time-resolved infrared spectral measurements and synchrotron SAXS/WAXD measurements

• Published in: Journal of physics. Conference series Vol. 184; no. 1; p. 012002
• Main Authors: Tashiro, Kohji, Nishiyama, Asami, Tsuji, Sawako, Hashida, Tomoko, Hanesaka, Makoto, Takeda, Shinichi, Weiyu, Cao, Reddy, Kummetha Raghunatha, Masunaga, Hiroyasu, Sasaki, Sono, Ito, Kazuki, Takata, Masaki
• Format: Journal Article
• Language: English
• Published: Bristol IOP Publishing 01.08.2009
• Subjects: Bonding strength; Coils; Crystal lattices; Crystallization; Domains; Evolution; Hydrogen bonding; Hydrogen bonds; Nylon 1010; Physics; Small angle X ray scattering; Spectra; Synchrotrons
• ISSN: 1742-6596; 1742-6588; 1742-6596
• DOI: 10.1088/1742-6596/184/1/012002

The structural evolution in the isothermal crystallization process of nylon 10/10 from the melt has been clarified concretely on the basis of the time-resolved infrared spectral measurement as well as the synchrotron wide-angle and small-angle X-ray scattering measurements. Immediately after the temperature jump from the melt to the crystallization point, the isolated domains consisting of the hydrogen-bonded random coils were formed in the melt, as revealed by Guinier plot of SAXS data and the infrared spectral data. With the passage of time these domains approached each other with stronger correlation as analyzed by Debye-Bueche equation. These domains transformed finally to the stacked crystalline lamellae, in which the conformationally-regularized methylene segments of the CO sides were connected each other by stronger intermolecular hydrogen bonds to form the crystal lattice.