Novel Nano-Structured Silica-Based Electrolytes Containing Quaternary Ammonium Iodide Moieties
A series of new hybrid organic‐inorganic molecules were prepared either by grafting of aminopropyltriethoxysilane (APTS) on silica nanoparticles followed by quaternarization of the nitrogen with ethyl, heptyl and isopropyl iodides or by grafting of N,N,N‐triethyl‐3‐(triethoxysilyl)propan‐1‐aminium i...
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Published in | Advanced functional materials Vol. 17; no. 16; pp. 3200 - 3206 |
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Main Authors | , , , , , |
Format | Journal Article |
Language | English |
Published |
Weinheim
WILEY-VCH Verlag
05.11.2007
WILEY‐VCH Verlag Wiley |
Subjects | |
Online Access | Get full text |
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Summary: | A series of new hybrid organic‐inorganic molecules were prepared either by grafting of aminopropyltriethoxysilane (APTS) on silica nanoparticles followed by quaternarization of the nitrogen with ethyl, heptyl and isopropyl iodides or by grafting of N,N,N‐triethyl‐3‐(triethoxysilyl)propan‐1‐aminium iodide and N,N,N‐tridodecyl‐3‐(triethoxysilyl)propan‐1‐aminium iodide onto the silica nanoparticles. These new materials were used as iodide sources in the preparation of electrolyte solutions for dye‐sensitized solar cells (DSSCs). The performance of DSSCs was studied as a function of the nature of the solvent, the nature of the dye, the concentration of the modified silica in the electrolyte system and the silica content introduced during the hybrid synthesis. An efficiency of 8.5 % was obtained for solar cells containing the triethyl ammonium iodide salt at a concentration of 1 M in either acetonitrile (AN) or 3‐methoxypropionitrile (MPN) under an illumination of 10 mW cm–2, the equivalent of 0.1 Sun at AM 1.5G. At 1 Sun (100 mW cm–2, efficiencies of 6.6 % and 5.1 % were recorded for the AN and MPN‐based electrolytes, respectively.
A new family of nanosized silica‐based quaternary ammonium iodide salts have been synthesized and applied as iodide sources in the Dye Sensitized Solar Cells, yielding high efficiencies at low irradiance and indicating their suitability for use in devices for indoor applications. |
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Bibliography: | Discovery, Linkage International Swiss National Science Foundation ArticleID:ADFM200700391 istex:CABB36A82AB8A3AD111B35A21A1353D5EC3FC1DA Centre of Excellence (Australian Centre for Electromaterials Science) ark:/67375/WNG-ZPCVFDH7-4 S.C., Y.B.C., and L.S. thank the Australian Research Council for financial support through the Discovery, Linkage International and Centre of Excellence (Australian Centre for Electromaterials Science) programs. S.M.Z. and M.G. thank The Swiss National Science Foundation for the financial support. Australian Research Council ObjectType-Article-2 SourceType-Scholarly Journals-1 ObjectType-Feature-1 content type line 23 |
ISSN: | 1616-301X 1616-3028 |
DOI: | 10.1002/adfm.200700391 |