Enthalpies of Solution and Enthalpies of Solvation in Water: The Anion Effect in Ionic Liquids with Common 1-Ethyl-3-methyl-imidazolium Cation

• Published in: Journal of solution chemistry Vol. 44; no. 3-4; pp. 811 - 823
• Main Authors: Varfolomeev, Mikhail A., Khachatrian, Artashes A., Akhmadeev, Bulat S., Solomonov, Boris N., Yermalayeu, Andrei V., Verevkin, Sergey P.
• Format: Journal Article
• Language: English
• Published: New York Springer US 01.04.2015
• Subjects: Anions; Aqueous solutions; Cations; Chemistry; Chemistry and Materials Science; Condensed Matter Physics; Correlation; Enthalpy; Geochemistry; Hydrogen bonding; Industrial Chemistry/Chemical Engineering; Inorganic Chemistry; Ionic liquids; Oceanography; Physical Chemistry; Solvation; Enthalpy of solvation; Solution calorimetry; Intermolecular interactions; Enthalpy of solution; Anion; Structure–property relations; Ionic liquid
• ISSN: 0095-9782; 1572-8927
• DOI: 10.1007/s10953-015-0328-y

Thermochemical studies of ionic liquids (ILs) in aqueous solution were carried out using solution calorimetry. Heat effects of dissolution in water at 298.15 K and molar limiting enthalpies of solution were measured for ILs having a common cation, 1-ethyl-3-methyl-imidazolium, connected with different anions: diethylphosphate, ethylsulfate, tetracyanoborate, thiocyanate, and trifluoroacetate. Molar enthalpies of solvation of ILs in water were derived from experimental data for solution and vaporization enthalpies. Enthalpic data were correlated with ionic liquid specific parameters and descriptors. The best correlation was observed with hydrogen-bonding interaction energies. This result confirmed that hydrogen bonding is one of the main types of intermolecular interactions inherent for ILs in aqueous solutions.