Synthesis and Hydrogen Storage Properties of Palladium Nanoparticle–Organic Frameworks

We report a simple synthesis of aggregates of individual Pd colloidal nanoparticles linked by bridging ligands that may be used to advance the strong hydrogen storage properties of palladium nanoparticles. The aggregates were characterized by transmission electron microscopy and infrared spectroscop...

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Bibliographic Details
Published inJournal of inorganic and organometallic polymers and materials Vol. 24; no. 1; pp. 208 - 213
Main Authors Yamamoto, Yuki, Miyachi, Mariko, Yamanoi, Yoshinori, Minoda, Ai, Maekawa, Shunsuke, Oshima, Shinji, Kobori, Yoshihiro, Nishihara, Hiroshi
Format Journal Article
LanguageEnglish
Published Boston Springer US 01.01.2014
Subjects
Aggregates
Chemistry
Chemistry and Materials Science
Hydrogen storage
Infrared spectroscopy
Inorganic Chemistry
Ligands
Nanoparticles
Organic Chemistry
Organometallic polymers
Palladium
Polymer Sciences
Synthesis
Bridging ligand
Particle assemblies
Hydrogen storage
Palladium nanoparticle
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Summary:We report a simple synthesis of aggregates of individual Pd colloidal nanoparticles linked by bridging ligands that may be used to advance the strong hydrogen storage properties of palladium nanoparticles. The aggregates were characterized by transmission electron microscopy and infrared spectroscopy. The bridged aggregates showed up to 1.0 wt% hydrogen absorption, about 6.7 times that of pristine isocyanide-protected Pd nanoparticles.
Bibliography:ObjectType-Article-2
SourceType-Scholarly Journals-1
ObjectType-Feature-1
content type line 23
ISSN:1574-1443
1574-1451
DOI:10.1007/s10904-013-9925-7