Contribution of dissolved sulfates and sulfites in hydrogen sulfide emission from stagnant water bodies in Sri Lanka

• Published in: Chemosphere (Oxford) Vol. 52; no. 5; pp. 901 - 907
• Main Authors: Kularatne, K.I.A., Dissanayake, D.P., Mahanama, K.R.R.
• Format: Journal Article
• Language: English
• Published: Oxford Elsevier Ltd 01.08.2003; Elsevier
• Subjects: Applied sciences; Atmospheric pollution; Dispersed sources and other; Dissolved oxygen; Dissolved sulfide; Exact sciences and technology; H 2S release; Hydrogen Sulfide - analysis; Hydrogen Sulfide - chemistry; Hydrogen-Ion Concentration; Linear Models; Oxygen - analysis; Oxygen - chemistry; Pollution; Pollution sources. Measurement results; Solubility; Speciation; Sri Lanka; Statistics as Topic; Sulfates - analysis; Sulfates - chemistry; Sulfites - analysis; Sulfites - chemistry; Temperature; Water Pollutants - analysis; Water pollution; Asia; Sri Lanka; Dissolved sulfide; Water pollution; H 2S release; Dissolved oxygen; Speciation; Microbial activity; Sulfites; Air water interface; Sulfates; Hydrogen sulfide; Biogenic factor; Sulfides; H2S release; Biotransformation; Stagnant water; Volatilization; Pollution source; Air pollution
• ISSN: 0045-6535; 1879-1298
• DOI: 10.1016/S0045-6535(03)00259-5

Accumulation of sulfur-containing compounds and their bacterial mediated reductions have led to the emission of pungent odors from stagnant water bodies. This study is focused on the contribution of inorganic sulfur compounds in the emission of hydrogen sulfide. The measured dissolved oxygen levels have demonstrated good negative correlations with the dissolved sulfide levels implying the oxygen deficiency is the key for the reduction of sulfate ion and sulfite ion to sulfide ion. Particularly, the dissolved molar fractions of sulfide from the total dissolved sulfur compounds (sulfates, sulfites and sulfides) have a very good correlation with the dissolved oxygen for the stagnant water bodies except the artificially aerated prawn farms. For the stagnant water bodies with significant correlations, linear regressions are reported for them to be utilized in estimating one component of the regression from the measurement of the other. The measured data were further utilized to estimate the levels of hydrogen sulfide gas. The pH of the water bodies has confined much of the dissolved sulfides in the form of bisulfide ion and they can be easily escaped to the atmosphere upon acidification due to industrial discharges and/or acidic precipitations. The estimated levels of hydrogen sulfide just above the water surface were plotted for the most polluted stagnant water body in Sri Lanka for the pH range of 5–10 and temperature range of 25–35 °C.