Screening test for aqueous solvents used in CO2 capture: K2CO3 used with twelve different rate promoters

• Published in: The Korean journal of chemical engineering Vol. 31; no. 1; pp. 125 - 131
• Main Authors: Park, Sangwon, Song, Ho-Jun, Lee, Min-Gu, Park, Jinwon
• Format: Journal Article
• Language: English
• Published: Boston Springer US 01.01.2014; 한국화학공학회
• Subjects: Biotechnology; Catalysis; Chemistry; Chemistry and Materials Science; Industrial Chemistry/Chemical Engineering; Materials Science; Separation Technology; Thermodynamics; 화학공학; Rate Promoter; Absorption; K; CO; Solution
• ISSN: 0256-1115; 1975-7220
• DOI: 10.1007/s11814-013-0200-y

K 2 CO 3 solution is widely used in the CO 2 -capture industry. In particular, it has advantages for treating CO 2 in flue gas under high-temperature and high-pressure conditions. However, it has a lower CO 2 -loading capacity and slower absorption kinetics than those of amines, which are its major disadvantages. Thus, in this study, we investigated ten loading-rate promoters, five primary amines and five secondary amines, to develop higher CO 2 -loading capacity and faster absorption kinetics. The screening tests of the absorption and desorption processes were conducted at 70 °C and 90 °C, respectively. Based on the results, we concluded that all the amines used improved the CO 2 -loading and absorption kinetics compared with the use of K 2 CO 3 alone. At a certain value CO 2 loading, the respective performance of the primary and secondary amines was twice and thrice better, respectively, than the neat K 2 CO 3 solution. Thus, secondary amines had superior absorption capacity and absorption/desorption rate compared to primary amines. Among the secondary amines, pipecolic acid, sarcosine, and isonipecotic acid were determined as the most effective absorption rate promoters.