Optimizing the conditions for starch dry phosphorylation with sodium mono- and dihydrogen orthophosphate under heat and vacuum
Starch was phosphorylated by reaction with mono- and disodium hydrogen orthophosphate under dry conditions in a vacuum oven at 150-180¦C (800 mbar). Studying the different factors affecting the reaction showed that the optimal conditions for starch phosphorylation in the monoester form were: 3 h rea...
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Published in | Die Stärke Vol. 52; no. 4; pp. 095 - 100 |
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Main Authors | , , , |
Format | Journal Article |
Language | English |
Published |
Weinheim
WILEY-VCH Verlag GmbH
01.06.2000
WILEY‐VCH Verlag GmbH Wiley-VCH |
Subjects | |
Online Access | Get full text |
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Summary: | Starch was phosphorylated by reaction with mono- and disodium hydrogen orthophosphate under dry conditions in a vacuum oven at 150-180¦C (800 mbar). Studying the different factors affecting the reaction showed that the optimal conditions for starch phosphorylation in the monoester form were: 3 h reaction time, 160¦C reaction temperature and pH 6. The different types of starch gave different degrees of substitution; and amylose bound a higher amount of phosphate than amylopectin under similar reaction conditions. Both ash content and acidity of the phosphorylated starch products increased proportionally with the increase in the degree of substitution while the pH of the different modified starch products was nearly in the same range (pH 6.55-6.75). |
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Bibliography: | 2000S10195 Q02 istex:4AF4577954DFD0B2202F4BA18F04D9255F5CD5BA ArticleID:STAR95 ark:/67375/WNG-70DBV1MW-N |
ISSN: | 0038-9056 1521-379X |
DOI: | 10.1002/1521-379X(200006)52:4<095::AID-STAR95>3.0.CO;2-X |