Two- and Three-Dimensional Frameworks Constructed From Bicapped Keggin Clusters

The novel two‐ and three‐dimensional solid materials [Cu(en)2(H2O)]{PMoVI8VIV6O42[Cu(en)2][Cu0.5(en)]3}·5.5H2O and H3{VVMoVI8VIV6O42[Cu(en)2]4}[MoO4]2·14H2O (en = ethylenediamine) have been hydrothermally assembled and structurally characterized. Both networks are based on mixed Mo/V bicapped Keggin...

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Published inEuropean journal of inorganic chemistry Vol. 2003; no. 14; pp. 2578 - 2581
Main Authors Duan, Li-Mei, Pan, Cheng-Ling, Xu, Ji-Qing, Cui, Xiao-Bing, Xie, Feng-Tong, Wang, Tie-Gang
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 01.07.2003
WILEY‐VCH Verlag
Subjects
Cluster compounds
Crystal structure
Hydrothermal synthesis
Polyoxometalates
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Summary:The novel two‐ and three‐dimensional solid materials [Cu(en)2(H2O)]{PMoVI8VIV6O42[Cu(en)2][Cu0.5(en)]3}·5.5H2O and H3{VVMoVI8VIV6O42[Cu(en)2]4}[MoO4]2·14H2O (en = ethylenediamine) have been hydrothermally assembled and structurally characterized. Both networks are based on mixed Mo/V bicapped Keggin clusters interconnected through the transition metal complex moieties. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)
Bibliography:istex:7B9C29BAD320BDEBF98D06E44A9588483A1A74D9
ArticleID:EJIC200300070
ark:/67375/WNG-QLBSTMJ2-5
ISSN:1434-1948
1099-0682
DOI:10.1002/ejic.200300070