Ruthenium(II) and iridium(III) complexes featuring NHC-sulfonate chelate

Three new complexes bearing a chelating (κ(2)C,O) NHC-SO3 ligand have been prepared. An original method for the synthesis of the imidazolium-sulfonate NHC precursor is described. The 5-membered ruthena- and irida-cycle containing complexes were fully characterized and evaluated in a series of cataly...

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Published inDalton transactions : an international journal of inorganic chemistry Vol. 44; no. 40; pp. 17467 - 17472
Main Authors Rajaraman, A, Sahoo, A R, Hild, F, Fischmeister, C, Achard, M, Bruneau, C
Format Journal Article
LanguageEnglish
Published England Royal Society of Chemistry 01.01.2015
SeriesDalton Transactions
Subjects
Bearing
Catalysis
Catalysts
Chelating
Chemical Sciences
Coordination chemistry
Coordination compounds
Inorganic chemistry
Ligands
Organic chemistry
Precursors
Synthesis
Transformations
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Summary:Three new complexes bearing a chelating (κ(2)C,O) NHC-SO3 ligand have been prepared. An original method for the synthesis of the imidazolium-sulfonate NHC precursor is described. The 5-membered ruthena- and irida-cycle containing complexes were fully characterized and evaluated in a series of catalytic transformations involving hydrogen auto-transfer processes.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
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ISSN:1477-9226
1477-9234
DOI:10.1039/c5dt02867a