Mechanical, Thermal and Water Absorption Properties of Kenaf-Fiber-Based Polypropylene and Poly(Butylene Succinate) Composites

• Published in: Journal of polymers and the environment Vol. 21; no. 1; pp. 293 - 302
• Main Authors: Lee, J. M., Mohd Ishak, Z. A., Mat Taib, R., Law, T. T., Ahmad Thirmizir, M. Z.
• Format: Journal Article
• Language: English
• Published: Boston Springer US 01.03.2013; Springer Nature B.V
• Subjects: Adhesion; Biodegradation; Chemistry; Chemistry and Materials Science; Compatibilizers; Composite materials; Cost engineering; Environmental Chemistry; Environmental Engineering/Biotechnology; Fibers; Industrial Chemistry/Chemical Engineering; Kenaf; Materials Science; Mechanical properties; Moisture absorption; Original Paper; Polyesters; Polymer matrix composites; Polymer Sciences; Polypropylene; Polypropylenes; Thermodynamics; Water absorption; Poly(butylene succinate); Polypropylene; Compatibilizer; Natural fiber; Interface
• ISSN: 1566-2543; 1572-8919; 1572-8900
• DOI: 10.1007/s10924-012-0516-4

The use of composites made from non-biodegradable conventional plastic materials (e.g., polypropylene, PP) is creating global environmental concern. Biodegradable plastics such as poly(butylene succinate) (PBS) are sought after to reduce plastic waste accumulation. Unfortunately, these types of plastics are very costly; therefore, natural lignocellulosic fibers are incorporated to reduce the cost. Kenaf fibers are also incorporated into PP and PBS for reinforcing purposes and they have low densities, high specific properties and renewable sourcing. However without good compatibilization, the interfacial adhesion between the matrix and the fibers is poor due to differences in polarity between the two materials. Maleic anhydride-grafted compatibilizers may be introduced into the system to improve the matrix-fiber interactions. The overall mechanical, thermal and water absorption properties of PP and PBS composites prepared with 30 vol.% short kenaf fibers (KFs) using a twin-screw extruder were being investigated in this study. The flexural properties for both types of composites were enhanced by the addition of compatibilizer, with improvements of 56 and 16 % in flexural strength for the PP/KF and PBS/KF composites, respectively. Good matrix-fiber adhesion was also observed by scanning electron microscopy. However, the thermal stability of the PBS/KF composites was lower than that of the PP/KF composites. This result was confirmed by both DSC and TGA thermal analysis tests. The water absorption at equilibrium of a PBS composite filled with KFs is inherently lower than of a PP/KF composite because the water molecules more readily penetrate the PP composites through existing voids between the fibers and the matrix. Based on this research, it can be concluded that PBS/KF composites are good candidates for replacing PP/KF composites in applications whereby biodegradability is essential and no extreme thermal and moisture exposures are required.