Water accelerated allylation of aldehydes by using water tolerant Grignard-type allylating agents from allylmagnesium chloride and various metallic salts

Some water-tolerant allylating agents prepared in situ from allylmagnesium chloride and bismuth trichloride, tin tetrachloride, tin dichloride, antimony trichloride, indium trichloride, or nickel dichloride reacted with aldehydes in THF-H2O to afford the desired homoallylic alcohols in good yields....

Full description

Saved in:
Bibliographic Details
Published inChemistry letters no. 3; pp. 376 - 377
Main Authors Fukuma, T, Lock, S, Miyoshi, N, Wada, M
Format Journal Article
LanguageEnglish
Published TOKYO Chemical Soc Japan 01.03.2002
Subjects
Chemistry
Chemistry, Multidisciplinary
Physical Sciences
Science & Technology
CARBON BOND FORMATION
TIN
MAGNESIUM
UNIT
AQUEOUS-MEDIA
ORGANIC-REACTIONS
Online AccessGet more information

Cover

More Information
Summary:Some water-tolerant allylating agents prepared in situ from allylmagnesium chloride and bismuth trichloride, tin tetrachloride, tin dichloride, antimony trichloride, indium trichloride, or nickel dichloride reacted with aldehydes in THF-H2O to afford the desired homoallylic alcohols in good yields. The present reaction proceeded more smoothly than that under non-aqueous media.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.2002.376