Water accelerated allylation of aldehydes by using water tolerant Grignard-type allylating agents from allylmagnesium chloride and various metallic salts
Some water-tolerant allylating agents prepared in situ from allylmagnesium chloride and bismuth trichloride, tin tetrachloride, tin dichloride, antimony trichloride, indium trichloride, or nickel dichloride reacted with aldehydes in THF-H2O to afford the desired homoallylic alcohols in good yields....
Saved in:
Published in | Chemistry letters no. 3; pp. 376 - 377 |
---|---|
Main Authors | , , , |
Format | Journal Article |
Language | English |
Published |
TOKYO
Chemical Soc Japan
01.03.2002
|
Subjects | |
Online Access | Get more information |
Cover
Loading…
Summary: | Some water-tolerant allylating agents prepared in situ from allylmagnesium chloride and bismuth trichloride, tin tetrachloride, tin dichloride, antimony trichloride, indium trichloride, or nickel dichloride reacted with aldehydes in THF-H2O to afford the desired homoallylic alcohols in good yields. The present reaction proceeded more smoothly than that under non-aqueous media. |
---|---|
ISSN: | 0366-7022 1348-0715 |
DOI: | 10.1246/cl.2002.376 |