SAFT-γ force field for the simulation of molecular fluids: 8. Hetero-segmented coarse-grained models of perfluoroalkylalkanes assessed with new vapour-liquid interfacial tension data

• Published in: Molecular physics Vol. 114; no. 18; pp. 2597 - 2614
• Main Authors: Morgado, Pedro, Lobanova, Olga, Müller, Erich A., Jackson, George, Almeida, Miguel, Filipe, Eduardo J. M.
• Format: Journal Article
• Language: English
• Published: Taylor & Francis 16.09.2016
• Subjects: coarse graining; Computational fluid dynamics; Computer simulation; Fluids; interfacial properties; intermolecular potential; Liquids; Molecular simulation; Surface tension; Temperature dependence; Thermodynamic properties; Vapor pressure
• ISSN: 0026-8976; 1362-3028
• DOI: 10.1080/00268976.2016.1218077

The air-liquid interfacial behaviour of linear perfluoroalkylalkanes (PFAAs) is reported through a combined experimental and computer simulation study. The surface tensions of seven liquid PFAAs (perfluorobutylethane, F 4 H 2 ; perfluorobutylpentane, F 4 H 5 ; perfluorobutylhexane, F 4 H 6 , perfluorobutyloctane, F 4 H 8 ; perfluorohexylethane, F 6 H 2 ; perfluorohexylhexane, F 6 H 6 ; and perfluorohexyloctane, F 6 H 8 ) are experimentally determined over a wide temperature range (276-350 K). The corresponding surface thermodynamic properties and the critical temperatures of the studied compounds are estimated from the temperature dependence of the surface tension. Experimental density and vapour pressure data are employed to parameterize a generic heteronuclear coarse-grained intermolecular potential of the SAFT-γ family for PFAAs. The resulting force field is used in direct molecular-dynamics simulations to predict the experimental tensions with quantitative agreement and to explore the conformations of the molecules in the interfacial region revealing a preferential alignment of the PFAA molecules towards the interface and an enrichment of the perfluoro groups at the outer interface region.