A novel one step synthesis of trans-1,4,6,9-tetraazabicyclo[4.4.0]decane over TiO2/zeolite composite photocatalysts

A novel one step inter-molecular cyclization of ethanol and ethylenediamine towards the formation of trans-1,4,6,9-tetraazabicyclo[4.4.0]decane (TAD) 3 has been achieved for the first time over TiO2/zeolite composite photocatalysts using solar/artificial light at ambient temperature.

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Bibliographic Details
Published inChemistry letters no. 2; pp. 236 - 237
Main Authors Rao, KVS, Srinivas, B, Prasad, AR, Subrahmanyam, M
Format Journal Article
LanguageEnglish
Published TOKYO Chemical Soc Japan 01.02.2002
Subjects
Chemistry
Chemistry, Multidisciplinary
Physical Sciences
Science & Technology
OXIDATION
PHOTO-KOLBE REACTION
SEMICONDUCTOR
RESONANCE
BIPHENYL
ALKYLATION
ETHANOL
ZEOLITES
ACETIC-ACID
TIO2
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Summary:A novel one step inter-molecular cyclization of ethanol and ethylenediamine towards the formation of trans-1,4,6,9-tetraazabicyclo[4.4.0]decane (TAD) 3 has been achieved for the first time over TiO2/zeolite composite photocatalysts using solar/artificial light at ambient temperature.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.2002.236