Experimental Investigation on Petroleum Sludge Valorization into Fuel via Pyrolysis Process

• Published in: Waste and biomass valorization Vol. 12; no. 4; pp. 2131 - 2143
• Main Authors: Bellahcene, Amal, Hachemi, Madjid, Largeau, Jean-François, Tarabet, Lyes, Burnens, Gaëtan, Khiari, Karim, Tazerout, Mohand
• Format: Journal Article
• Language: English
• Published: Dordrecht Springer Netherlands 01.04.2021; Springer Nature B.V; Springer
• Subjects: Air pollution; Aluminum oxide; Batch reactors; Calorific value; Catalysts; Catalytic converters; Diesel; Diesel engines; Diesel fuels; Engineering; Engineering Sciences; Environment; Environmental degradation; Environmental effects; Environmental Engineering/Biotechnology; Environmental Sciences; Flash point; Hydrocarbons; Industrial Pollution Prevention; Nuclear fuels; Oil; Original Paper; Pollutants; Pyrolysis; Pyrolysis products; Renewable and Green Energy; Sludge; Titanium dioxide; Waste Management/Waste Technology; Pyrolysis; Oil sludge; Diesel fuel; Catalyst
• ISSN: 1877-2641; 1877-265X
• DOI: 10.1007/s12649-020-01155-6

Oil sludge (OS) has been of key concern due to its continuing effect on the environment degradation. The huge quantities thrown yearly of this waste contain a high proportion of hydrocarbons which are valuable for recovery. This study focused on the oil sludge conversion into a fuel for a diesel engine by thermal/catalytic pyrolysis process. The experiments were conducted at atmospheric pressure in a batch reactor operated without and with two catalyst types: TiO 2 (3 and 5 wt%) and Al 2 O 3 (3 and 5 wt%). Overall all test conditions followed in the OS pyrolysis, a considerable liquid fraction is recovered (around 70%), as compared to the gaseous fraction (around 25%) and the solid residue (around 5%). The characterization of the pyrolytic oil samples, containing approximately 11.70% of oxygen, showed also that the use of 5% of Al 2 O 3 catalyst in the OS cracking provide the best fuel quality with a minimum viscosity value (3.5 mm 2 /s), a maximum heating value (45.72 MJ/kg) with a hydrocarbon compounds in the range (C 7 –C 32 ) which are detailed by GC–MS analysis. The others properties (density, flash point, pour point and cloud point) are found to be close to those of diesel fuel. Also, the catalysts effect is studied on the others pyrolysis products. The obtained results allow to predict the good usability as a diesel like fuel. Further tests to control engine performance and pollutant emissions could be done Graphic Abstract