Effect of thermal insulation on microstructural homogeneity and onset temperature of flash sintered materials

• Published in: Journal of the European Ceramic Society Vol. 41; no. 15; pp. 7807 - 7815
• Main Authors: Storion, Ana G., Lavagnini, Isabela R., Campos, João V., da Silva, João G.P., Maestrelli, Sylma C., Pallone, Eliria M.J.A.
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 01.12.2021
• Subjects: Flash sintering; Grain size; Microstructure evolution; Thermal insulation; Zinc oxide; Grain size; Zinc oxide; Flash sintering; Microstructure evolution; Thermal insulation
• ISSN: 0955-2219; 1873-619X
• DOI: 10.1016/j.jeurceramsoc.2021.08.060

•TIFS improved energy savings in 78 % compared to FS by reducing the onset temperature.•The microstructure homogeneity was improved by avoiding radiation heat losses with TIFS.•A model was proposed to estimate the sample temperature with/without thermal insulation.•The proposed model suggested the final temperature barely differ between FS and TIFS.•Absorbed water can trigger the flash event at lower furnace temperatures. The present work aimed to reduce the microstructure heterogeneity inherent to flash sintering by using alumina blankets as a thermal insulator around ZnO cylindrical samples during the sintering process, under different electric field conditions. Thermal insulation significantly reduced the flash onset temperature and the grain size heterogeneity. For higher electric fields, a temperature reduction as high as 480 °C was observed, which also led to lower densification. These findings were discussed in terms of changes in the heat loss dynamics coupled with the adsorbed water retention, both promoted by the applied thermal insulation. A model to estimate the temperature at stage III of flash sintering was proposed. The final temperature reached with thermal insulation did not differ significantly from the ones without it. Thus, thermal insulation could represent an alternative route to flash sinter materials with lower furnace temperatures with energy savings up to 78 % and a more homogeneous microstructure.