Anionic Polymerization of 1, 3-Cyclohexadiene-Arrangement of 1, 2-and 1, 4-Units
The arrangement of the 1, 2-and 1, 4-units of poly (1, 3-cyclohexadiene) (PCHD), obtained by anionic polymerization with the n-butyllithium (n-BuLi) /N, N, N′, N′-tetramethyl-ethylenediamine (TMEDA) initiator system, was investigated. The 1, 2-/1, 4-unit molar ratio of PCHD was about 1 during the po...
Saved in:
| Published in | KOBUNSHI RONBUNSHU Vol. 61; no. 3; pp. 200 - 202 |
|---|---|
| Main Author | |
| Format | Journal Article |
| Language | English Japanese |
| Published |
The Society of Polymer Science, Japan
01.01.2004
|
| Subjects | |
| Online Access | Get full text |
Cover
Loading…
| Abstract | The arrangement of the 1, 2-and 1, 4-units of poly (1, 3-cyclohexadiene) (PCHD), obtained by anionic polymerization with the n-butyllithium (n-BuLi) /N, N, N′, N′-tetramethyl-ethylenediamine (TMEDA) initiator system, was investigated. The 1, 2-/1, 4-unit molar ratio of PCHD was about 1 during the polymerization of 1, 3-cyclohexadiene with the n-BuLi/TMEDA (4/5) system. Each polymer sample showed only one glass transition temperature (Tg), independent of the number average molecular weight (Mn). This method allows the preparation of poly (1, 3-cyclohexadiene) s having quasi alternated 1, 2-/1, 4-unit sequences in the polymer chain. |
|---|---|
| AbstractList | The arrangement of the 1, 2-and 1, 4-units of poly (1, 3-cyclohexadiene) (PCHD), obtained by anionic polymerization with the n-butyllithium (n-BuLi) /N, N, N′, N′-tetramethyl-ethylenediamine (TMEDA) initiator system, was investigated. The 1, 2-/1, 4-unit molar ratio of PCHD was about 1 during the polymerization of 1, 3-cyclohexadiene with the n-BuLi/TMEDA (4/5) system. Each polymer sample showed only one glass transition temperature (Tg), independent of the number average molecular weight (Mn). This method allows the preparation of poly (1, 3-cyclohexadiene) s having quasi alternated 1, 2-/1, 4-unit sequences in the polymer chain. |
| Author | NATORI, Itaru |
| Author_xml | – sequence: 1 fullname: NATORI, Itaru organization: Advanced Products Laboratory, Chemicals R & D Division, Asahi Kasei Corporation |
| BookMark | eNo9kMtuwjAQRa2KSqWUXT8gH4CpH4ljLxGiDwmpLOjaMmYCboNd2Vk0_fqaBrGZGdnnjEb3Ho188IDQIyVzylT19BVi8HNB54yQGzSmUlJcCVmN0JhwKTCjUtyhaUpuR0ilCFVEjNFm4V3wzhab0PYniO7XdPmhCE1BZwXHy9624Qg_Zu_AA17EaPwBTuC7C8Kw8fvzUOIP77r0gG4b0yaYXvoEbZ9X2-UrXr-_vC0Xa2y5Ih2moiaSS0ZKKcuybvaWNFDXBlQtrBSw40oIoyoJFZgKWD4WbAMy29lkfIJmw1obQ0oRGv0d3cnEXlOiz3no_zy0oDrnkfHVgH-mzhzgCpvYOdvCAFNVl2eBDyV71397NFGD539WhmxU |
| CitedBy_id | crossref_primary_10_1002_polb_20798 |
| ContentType | Journal Article |
| Copyright | The Society of Polymer Science, Japan |
| Copyright_xml | – notice: The Society of Polymer Science, Japan |
| DBID | AAYXX CITATION |
| DOI | 10.1295/koron.61.200 |
| DatabaseName | CrossRef |
| DatabaseTitle | CrossRef |
| DatabaseTitleList | |
| DeliveryMethod | fulltext_linktorsrc |
| Discipline | Engineering |
| EISSN | 1881-5685 |
| EndPage | 202 |
| ExternalDocumentID | 10_1295_koron_61_200 article_koron1974_61_3_61_3_200_article_char_en |
| GroupedDBID | 5GY ACGFS ACIWK AENEX ALMA_UNASSIGNED_HOLDINGS CS3 DU5 JSF KQ8 RJT AAYXX CITATION |
| ID | FETCH-LOGICAL-c390t-167083820488447fdc0fe77ae976c86eb3966a958e5ea5e2906ecfe8c3967023 |
| ISSN | 0386-2186 |
| IngestDate | Fri Aug 23 02:11:56 EDT 2024 Thu Aug 17 20:29:23 EDT 2023 |
| IsDoiOpenAccess | true |
| IsOpenAccess | true |
| IsPeerReviewed | true |
| IsScholarly | true |
| Issue | 3 |
| Language | English Japanese |
| LinkModel | OpenURL |
| MergedId | FETCHMERGED-LOGICAL-c390t-167083820488447fdc0fe77ae976c86eb3966a958e5ea5e2906ecfe8c3967023 |
| OpenAccessLink | https://www.jstage.jst.go.jp/article/koron1974/61/3/61_3_200/_article/-char/en |
| PageCount | 3 |
| ParticipantIDs | crossref_primary_10_1295_koron_61_200 jstage_primary_article_koron1974_61_3_61_3_200_article_char_en |
| PublicationCentury | 2000 |
| PublicationDate | 2004-01-01 |
| PublicationDateYYYYMMDD | 2004-01-01 |
| PublicationDate_xml | – month: 01 year: 2004 text: 2004-01-01 day: 01 |
| PublicationDecade | 2000 |
| PublicationTitle | KOBUNSHI RONBUNSHU |
| PublicationTitleAlternate | KOBUNSHI RONBUNSHU |
| PublicationYear | 2004 |
| Publisher | The Society of Polymer Science, Japan |
| Publisher_xml | – name: The Society of Polymer Science, Japan |
| References | 12) 名取至, 高分子論文集, 60, 121 (2003). 14) 名取至, 高分子論文集, 60, 232 (2003). 1) I. Natori, Macromolecules, 30, 3696 (1997). 2) I. Natori and S. Inoue, Macromolecules, 31, 982 (1998). 3) I. Natori and S. Inoue, Macromolecules, 31, 4687 (1998 6) 今泉公夫, 名取至, 日本化学会誌, 1999, 293. 4) I. Natori, K. Imaizumi, H. Yamagishi, and M. Kazunori, J. Polym. Sci., Part B, Polym. Phys., 36, 1657 (1998). 9) I. Natori. Polym. J., 34. 973 (2002). 13) 名取至, 山岸秀之, 高分子論文集, 60, 138 (2003). 11) I. Natori, Polym. J., 35, 622 (2003). 5) 名取至, 高分子論文集, 56, 480 (1999). 8) K. Imaizumi, T. Ono, I. Natori, S. Sakurai, and T. Takeda, J. Polym. Sci., Part B, Polym. Phys., 39, 13 (2001). 7) I. Natori and K. Imaizumi, Macromol. Symp., 157, 143 (2000). 10) 名取至, 高分子論文集, 60, 115 (2003). |
| References_xml | |
| SSID | ssib005901906 ssib000972329 ssj0059176 ssib014653950 ssib053392992 |
| Score | 1.6026921 |
| Snippet | The arrangement of the 1, 2-and 1, 4-units of poly (1, 3-cyclohexadiene) (PCHD), obtained by anionic polymerization with the n-butyllithium (n-BuLi) /N, N, N′,... |
| SourceID | crossref jstage |
| SourceType | Aggregation Database Publisher |
| StartPage | 200 |
| SubjectTerms | 1, 2-Unit 1, 4-Unit Arrangement Poly (1, 3-cyclohexadiene) Polymer Chain Structure |
| Title | Anionic Polymerization of 1, 3-Cyclohexadiene-Arrangement of 1, 2-and 1, 4-Units |
| URI | https://www.jstage.jst.go.jp/article/koron1974/61/3/61_3_200/_article/-char/en |
| Volume | 61 |
| hasFullText | 1 |
| inHoldings | 1 |
| isFullTextHit | |
| isPrint | |
| ispartofPNX | KOBUNSHI RONBUNSHU, 2004/03/25, Vol.61(3), pp.200-202 |
| link | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwpV1Lb9QwELZKywEOiKcolCoHOIEXO04c54K0rYq2rdiFsiv1FjmJLSjVbrWkEu2vZ8Z20iygisLFshI7smYm42_seRDy0sAmZ5kG26RSmgKktlTXMqU2K2vJjCwtx-DkD2M5miUHx-nxlduYiy5pykF1-ce4kn_hKjwDvmKU7A04230UHkAf-AstcBjav-LxcP7VF7BZnF7gzctlh_84kk7Q3YvqdPHF_HB-XYYOl0uMJWjv_92gmOLRuesmFBHo9z5ePZzszMafR_uvjyZj15t1p8fD6eRo36mYRi_PV04Pkl9OD1AWW_dQ73OHy231infWPQtiGqKslKRYx8rvH15pKsVpKn3pnVar-hTrQXpEX0Uy1tttYxdv_bsij3PMefENszgMJB90k1ZSYwfCF24YB8uokLwQvoEZRfseA9hAXm6RjRjUETr-HX7qgVAsvNYDiRiN28uBzzEDXY53v35_T8HA9TfggRIhnAJW_La_3hWgc_sEsH7rJ-igy_Q-uRdsjmjo1_mArJ3oh-RuLxPlI_IxiFK0KkrRwkb8TXSdIIUhToywE4ToMZm-35vujmgotkErkbOGcpkBGleYx1klSWbrilmTZdoAXq2UNKUAw1jnqTKp0anBKgGmskbBbJgZiydkfb6Ym6ckAkRbVolmGh2UTV6Xoq5VKRizYMwKpjfJq5YwxZlPqVKgKQoE9JxEBgIBN8k7T7Vu1A35_ex_P_Cc3Ln6Z7bIerM8Ny8AgzblthOhn4c8gWg |
| link.rule.ids | 315,783,787,27938,27939 |
| linkProvider | Colorado Alliance of Research Libraries |
| openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Anionic+Polymerization+of+1%2C+3-Cyclohexadiene-Arrangement+of+1%2C+2-and+1%2C+4-Units&rft.jtitle=KOBUNSHI+RONBUNSHU&rft.au=NATORI%2C+Itaru&rft.date=2004-01-01&rft.pub=The+Society+of+Polymer+Science%2C+Japan&rft.issn=0386-2186&rft.eissn=1881-5685&rft.volume=61&rft.issue=3&rft.spage=200&rft.epage=202&rft_id=info:doi/10.1295%2Fkoron.61.200&rft.externalDocID=article_koron1974_61_3_61_3_200_article_char_en |
| thumbnail_l | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=0386-2186&client=summon |
| thumbnail_m | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=0386-2186&client=summon |
| thumbnail_s | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=0386-2186&client=summon |