Modified Biochar—A Tool for Wastewater Treatment

• Published in: Energies (Basel) Vol. 13; no. 20; p. 5270
• Main Authors: Kopecký, Marek, Kolář, Ladislav, Konvalina, Petr, Strunecký, Otakar, Teodorescu, Florina, Mráz, Petr, Peterka, Jiří, Váchalová, Radka, Bernas, Jaroslav, Bartoš, Petr, Filipov, Feodor, Bucur, Daniel
• Format: Journal Article
• Language: English
• Published: Basel MDPI AG 01.10.2020
• Subjects: Adsorption; Agricultural production; Agrochemicals; biochar; Charcoal; Control; Crystallization; Developing countries; Distribution; Ecosystems; Eutrophication; Ferric chloride; fertilizer; Fertilizers; Fluidized bed reactors; Industrialized nations; Iron compounds; Iron phosphates; iron(III) phosphate; LDCs; Municipal wastewater; Phosphates; Phosphorus; Phosphorus removal; Precipitation; Purification; recycling; Sewage; Sludge; Sodium hydroxide; Struvite; Supply and demand; Wastewater facilities; Wastewater treatment; Wastewater treatment plants; Water quality; Water treatment; Watercourses; Czech Republic
• ISSN: 1996-1073; 1996-1073
• DOI: 10.3390/en13205270

Global deposits of concentrated phosphates, which are a necessary source for the production of phosphate fertilizers, are limited. These reserves keep getting thinner, and every day, large amounts of phosphorus end up in watercourses. In this study, we verified that modified biochar (saturated with FeCl3 solution and then neutralized with NaOH solution) can adsorb significant amounts of phosphorus from wastewater. Moreover, the agrochemical qualities of sludge water from a municipal wastewater treatment plant, struvite, phosphorus-saturated biochar, and iron(III) phosphate from a reused biochar filter were tested in this study. We determined the amount of mobile phosphorus as well as the amount of extractable phosphorus and its five fractions. It was found that modified biochar can hold one-third of the phosphorus amount contained in the commonly used agricultural fertilizer simple superphosphate (1 × 105 g of modified biochar captures up to 2.79 × 103 g of P). Moreover, plants can more easily access phosphorus biochar fractions than struvite, which is formed spontaneously during sludge management. The results of this research prove that the proposed method of recycling phosphorus from wastewater can be applied in technological practice.