Selective catalytic transfer hydrogenation of nitriles to primary amines using Pd/C

The catalytic transfer hydrogenation of (hetero)aryl nitriles using ammonium formate has been investigated in detail. In the presence of commercially available Pd/C, a straightforward and selective reduction is achieved without any additives under mild conditions. The Pd/C catalyzed transfer hydroge...

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Published inCatalysis science & technology Vol. 4; no. 3; pp. 629 - 632
Main Authors Vilches-Herrera, Marcelo, Werkmeister, Svenja, Junge, Kathrin, Börner, Armin, Beller, Matthias
Format Journal Article
LanguageEnglish
Published 01.01.2014
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Summary:The catalytic transfer hydrogenation of (hetero)aryl nitriles using ammonium formate has been investigated in detail. In the presence of commercially available Pd/C, a straightforward and selective reduction is achieved without any additives under mild conditions. The Pd/C catalyzed transfer hydrogenation of (hetero)aryl nitriles using ammonium formate has been investigated in detail.
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ISSN:2044-4753
2044-4761
DOI:10.1039/c3cy00854a