Evaluation of lyophility of carbon materials for electrodes of supercapacitors

The heats of wetting have been measured experimentally for some of the solvents used for the preparation of electrolytes of supercapacitors. For the first time, the heat of wetting has been measured for a new promising solvent—tributyl phosphate. Using acetonitrile as an example, the possible orient...

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Bibliographic Details
Published inPhysics of the solid state Vol. 58; no. 12; pp. 2555 - 2559
Main Authors Kompan, M. E., Agafonov, D. V., Bursian, A. E., Dmitriev, D. S., Mikryukova, M. A.
Format Journal Article
LanguageEnglish
Published Moscow Pleiades Publishing 01.12.2016
Springer
Springer Nature B.V
Subjects
Analysis
Capacitors
Electrolytes
Nitriles
Physics
Physics and Astronomy
Solid State Physics
Supercapacitors
Surface Physics and Thin Films
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Summary:The heats of wetting have been measured experimentally for some of the solvents used for the preparation of electrolytes of supercapacitors. For the first time, the heat of wetting has been measured for a new promising solvent—tributyl phosphate. Using acetonitrile as an example, the possible orientation of the molecule at the adsorbing surface has been investigated by the technique of surface-enhanced Raman scattering (SERS) (effect of giant enhancement of the scattering by a conducting surface). The calculated estimates have been obtained for the quantities found in the experiment.
ISSN:1063-7834
1090-6460
DOI:10.1134/S1063783416120118