3D Visualization of Morphological Evolution of Large Defects during Spark Plasma Sintering of Alumina Granules

• Published in: Advanced engineering materials Vol. 25; no. 18
• Main Authors: Okuma, Gaku, Endo, Masaya, Minagawa, Haruki, Inoue, Ryo, Kakisawa, Hideki, Kohata, Takuma, Osada, Toshio, Yamamoto, Takafumi, Azuma, Masaki, Takeuchi, Akihisa, Uesugi, Masayuki, Guillon, Olivier, Wakai, Fumihiro
• Format: Journal Article
• Language: English
• Published: 01.09.2023
• ISSN: 1438-1656; 1527-2648
• DOI: 10.1002/adem.202201534

The mechanical reliability of products must be assured for scaling up and production of complex‐shaped components by spark plasma sintering (SPS) of spray‐dried granules. The evolution of morphologies of pores and defects, which control the mechanical strength, is investigated by using synchrotron X‐ray multiscale tomography during SPS of alumina granules at 1300 °C. While large defects arising from the hierarchical granule packing structure cannot be removed by pressureless sintering, crack‐like defects and branched rodlike defects are almost eliminated by SPS at stresses higher than 30 and 50 MPa, respectively. But, small ellipsoidal porous regions, which may arise from aggregates or dimples of granules, cannot be removed even at a pressure of 50 MPa. A very large defect is also found by using micro‐CT. It is supposed that this defect is formed from a large void in loosely packed granules. The shrinkage of large voids and the elimination of crack‐like defects are explained by the theoretical prediction based on the continuum theory of sintering.