Understanding the Ni Migration in Solid Oxide Cell: A Coupled Experimental and Modeling Approach

• Published in: Journal of the Electrochemical Society Vol. 170; no. 3; pp. 34504 - 34516
• Main Authors: Rorato, Léa, Shang, Yijing, Yang, Shenglan, Hubert, Maxime, Couturier, Karine, Zhang, Lijun, Vulliet, Julien, Chen, Ming, Laurencin, Jérôme
• Format: Journal Article
• Language: English
• Published: IOP Publishing 01.03.2023; Electrochemical Society
• Subjects: Engineering Sciences; Solid Oxide Fuel Cell; modeling; Ni migration; Solid Oxide Electrolysis Cell; phase-field
• ISSN: 0013-4651; 1945-7111
• DOI: 10.1149/1945-7111/acc1a3

A long-term test of 2000 h has been carried out on a typical solid oxide cell in electrolysis mode at −1 A.cm −2 and 750 °C. The 3D reconstructions of the pristine and aged cermet have revealed a strong Ni depletion at the electrolyte interface. To explain this result, an electrochemical and phase-field model has been developed to simulate the Ni migration in Ni/YSZ electrode. For this purpose, a mechanism has been proposed that takes into account the impact of polarization on the Ni/YSZ wettability. In this approach, it assumes that the Ni/YSZ interfacial energy is changed by the concentration of oxygen vacancies in the electrochemical double layer. Thanks to the model, the Ni migration has been computed in the same condition than the experiment and complemented by a simulation in reverse condition in SOFC mode. In good agreement with the experiment, the simulations have revealed a strong Ni depletion at the electrolyte interface after operation under electrolysis current. On the contrary, a negligible Ni redistribution with a very slight Ni enrichment has been predicted at the electrolyte interface after SOFC operation. These results tend to prove the relevance of the mechanism. Highlights A mechanism is proposed to account for the Ni migration in SOCs electrodes. A multi-scale electrochemical and phase-field model has been built. Prediction of a strong Ni depletion in SOEC mode at the electrolyte interface. Prediction of a slight Ni enrichment in SOFC mode at the electrolyte interface. Simulations in good agreement with a long-term test performed in electrolysis mode.