Novel, electrolyte solutions comprising fully inorganic salts with high anodic stability for rechargeable magnesium batteries

Herein the first inorganic magnesium salt solution capable of highly reversible magnesium electrodeposition is presented. Synthesized by acid-base reaction of MgCl2 and Lewis acidic compounds such as AlCl3, this salt class demonstrates upwards of 99% Coulombic efficiency, deposition overpotential of...

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Published inChemical communications (Cambridge, England) Vol. 50; no. 2; pp. 243 - 245
Main Authors Doe, Robert E, Han, Ruoban, Hwang, Jaehee, Gmitter, Andrew J, Shterenberg, Ivgeni, Yoo, Hyun Deog, Pour, Nir, Aurbach, Doron
Format Journal Article
LanguageEnglish
Published England 01.01.2014
Subjects
Anodic
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Summary:Herein the first inorganic magnesium salt solution capable of highly reversible magnesium electrodeposition is presented. Synthesized by acid-base reaction of MgCl2 and Lewis acidic compounds such as AlCl3, this salt class demonstrates upwards of 99% Coulombic efficiency, deposition overpotential of <200 mV, and anodic stability of 3.1 V.
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USDOE Advanced Research Projects Agency - Energy (ARPA-E)
DE-AR0000062
ISSN:1359-7345
1364-548X
DOI:10.1039/c3cc47896c