Oxidation behaviors of CrNb, CrNbTi, and CrNbTaTi concentrated refractory alloys

• Published in: Intermetallics Vol. 140; p. 107374
• Main Authors: Butler, T.M., Senkov, O.N., Daboiku, T.I., Velez, M.A., Schroader, H.E., Ware, L.G., Titus, M.S.
• Format: Journal Article
• Language: English
• Published: Barking Elsevier Ltd 01.01.2022; Elsevier BV
• Subjects: Complex oxide; Density functional theory; High-entropy; Kinetics; Laves phase; Microstructure; Oxidation; Precipitates; Reaction kinetics; Refractory; Refractory alloys; Refractory; High-entropy; Complex oxide; Oxidation
• ISSN: 0966-9795; 1879-0216
• DOI: 10.1016/j.intermet.2021.107374

The 1200 °C oxidation behaviors of CrNb, CrNbTi and CrNbTaTi are reported. All alloys formed some combination of BCC and Laves phases. However, additions of Ti produced a unique inflection point where the microstructure inverts to a Ti-rich BCC matrix with Laves phase precipitates. Further additions of Ta to CrNbTi were found to increase the overall phase fraction of BCC phase. The oxidation kinetics for CrNb and CrNbTi were similar and nearly parabolic throughout the duration of exposure. CrNbTaTi exhibited inferior oxidation kinetics and mixed mode behavior throughout oxidation testing. All alloys formed intricate multi-phase oxide structures, consisting of a combination of both simple and complex oxides. The resulting microstructures are characterized using a variety of analytical techniques and the results are discussed relative to modeling predictions using ab initio density functional theory (DFT). •Additions of Ti and Ta to CrNb invert the microstructure and enhance ductility.•The oxidation kinetics for CrNb and CrNbTi were similar and parabolic.•CrNb, CrNbTi and CrNbTaTi all form multi-phase complex oxide structures.•Ab initio data suggests oxide formation competition with increased compositional complexity.