Thermodynamics of Molten MnS–CrS–FeS System at 1843 K

Phase equilibria in Fe–Cr–Mn–S quaternary system at 1843 K were investigated experimentally. Two liquid phases: molten metal alloy phase and molten sulfide phase were in equilibrium in this system at 1843 K. The equilibrium relations between molten metal alloy and sulfide phases were experimentally...

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Published inISIJ International Vol. 61; no. 9; pp. 2355 - 2359
Main Authors Lu, Yan, Miki, Takahiro
Format Journal Article
LanguageEnglish
Published The Iron and Steel Institute of Japan 15.09.2021
Subjects
activity
phase equilibrium
regular solution model
sulfide inclusion
thermodynamics
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Abstract Phase equilibria in Fe–Cr–Mn–S quaternary system at 1843 K were investigated experimentally. Two liquid phases: molten metal alloy phase and molten sulfide phase were in equilibrium in this system at 1843 K. The equilibrium relations between molten metal alloy and sulfide phases were experimentally measured. By using metal/sulfide equilibrium method, activity of constituents in molten MnS–CrS–FeS sulfide phase were determined. By utilizing regular solution model, activity curves of constituents in sulfide phase were estimated.
AbstractList Phase equilibria in Fe–Cr–Mn–S quaternary system at 1843 K were investigated experimentally. Two liquid phases: molten metal alloy phase and molten sulfide phase were in equilibrium in this system at 1843 K. The equilibrium relations between molten metal alloy and sulfide phases were experimentally measured. By using metal/sulfide equilibrium method, activity of constituents in molten MnS–CrS–FeS sulfide phase were determined. By utilizing regular solution model, activity curves of constituents in sulfide phase were estimated.
ArticleNumber ISIJINT-2020-741
Author Miki, Takahiro
Lu, Yan
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SubjectTerms activity
phase equilibrium
regular solution model
sulfide inclusion
thermodynamics
Title Thermodynamics of Molten MnS–CrS–FeS System at 1843 K
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