Highly efficient Tsuji-Trost allylation in water catalyzed by Pd-nanoparticles

Palladium nanoparticles stabilized by poly(vinylpyrrolidone) catalyze Tsuji-Trost allylations in water with very high turnover numbers. The di-allylation of methylene active compounds and the allylation of bio-based phenols was performed in high yield. The allylation of lignin showed a high selectiv...

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Published inChemical communications (Cambridge, England) Vol. 53; no. 37; pp. 5175 - 5178
Main Authors Llevot, A, Monney, B, Sehlinger, A, Behrens, S, Meier, M A R
Format Journal Article
LanguageEnglish
Published England Royal Society of Chemistry 2017
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Chemical Sciences
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Abstract Palladium nanoparticles stabilized by poly(vinylpyrrolidone) catalyze Tsuji-Trost allylations in water with very high turnover numbers. The di-allylation of methylene active compounds and the allylation of bio-based phenols was performed in high yield. The allylation of lignin showed a high selectivity towards the phenolic OH groups.
AbstractList Palladium nanoparticles stabilized by poly(vinylpyrrolidone) catalyze Tsuji-Trost allylations in water with very high turnover numbers. The di-allylation of methylene active compounds and the allylation of bio-based phenols was performed in high yield. The allylation of lignin showed a high selectivity towards the phenolic OH groups.
Author Monney, B
Sehlinger, A
Llevot, A
Meier, M A R
Behrens, S
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Snippet Palladium nanoparticles stabilized by poly(vinylpyrrolidone) catalyze Tsuji-Trost allylations in water with very high turnover numbers. The di-allylation of...
Palladium nanoparticles stabilized by poly(vinylpyrrolidone) catalyze Tsuji–Trost allylations in water with very high turnover numbers. The di-allylation of...
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SubjectTerms Chemical Sciences
Title Highly efficient Tsuji-Trost allylation in water catalyzed by Pd-nanoparticles
URI https://www.ncbi.nlm.nih.gov/pubmed/28439582
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