Highly efficient Tsuji-Trost allylation in water catalyzed by Pd-nanoparticles

Palladium nanoparticles stabilized by poly(vinylpyrrolidone) catalyze Tsuji-Trost allylations in water with very high turnover numbers. The di-allylation of methylene active compounds and the allylation of bio-based phenols was performed in high yield. The allylation of lignin showed a high selectiv...

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Published inChemical communications (Cambridge, England) Vol. 53; no. 37; pp. 5175 - 5178
Main Authors Llevot, A, Monney, B, Sehlinger, A, Behrens, S, Meier, M A R
Format Journal Article
LanguageEnglish
Published England Royal Society of Chemistry 2017
Subjects
Chemical Sciences
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Summary:Palladium nanoparticles stabilized by poly(vinylpyrrolidone) catalyze Tsuji-Trost allylations in water with very high turnover numbers. The di-allylation of methylene active compounds and the allylation of bio-based phenols was performed in high yield. The allylation of lignin showed a high selectivity towards the phenolic OH groups.
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ISSN:1359-7345
1364-548X
DOI:10.1039/c7cc02380d