Vacuum Ultraviolet Absorption and Photoelectron Spectra of Aliphatic Ketones

The vacuum ultraviolet absorption spectra down to 65000 cm−1 and Hel photoelectron spectra were measured for CH3CHO and RCOCH3 (R=CH3 to t-C4H9). Assignments of the absorption bands are proposed with the aid of photoelectron spectra and CNDO/2 type molecular orbital calculations. Special notice has...

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Published inBulletin of the Chemical Society of Japan Vol. 47; no. 4; pp. 958 - 961
Main Authors Ogata, Hitoshi, Kitayama, Jun, Koto, Masanori, Kojima, Shinji, Nihei, Yoshimasa, Kamada, Hitoshi
Format Journal Article
LanguageEnglish
Published Tokyo The Chemical Society of Japan 01.04.1974
Chemical Society of Japan
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Summary:The vacuum ultraviolet absorption spectra down to 65000 cm−1 and Hel photoelectron spectra were measured for CH3CHO and RCOCH3 (R=CH3 to t-C4H9). Assignments of the absorption bands are proposed with the aid of photoelectron spectra and CNDO/2 type molecular orbital calculations. Special notice has been paid to the similarity of the vibrational structure between the lowest ionization potential bands of photoelectron spectra and the second bands of vacuum ultraviolet absorption spectra.
ISSN:0009-2673
1348-0634
DOI:10.1246/bcsj.47.958