Continuous adsorption of Pb(II) and methylene blue by engineered graphite oxide coated sand in fixed-bed column

• Published in: Applied surface science Vol. 330; pp. 148 - 157
• Main Authors: Gong, Ji-Lai, Zhang, Yong-Liang, Jiang, Yan, Zeng, Guang-Ming, Cui, Zhi-Hui, Liu, Ke, Deng, Can-Hui, Niu, Qiu-Ya, Deng, Jiu-Hua, Huan, Shuang-Yan
• Format: Journal Article
• Language: English
• Published: 01.03.2015
• Subjects: Adsorption; Exhaustion; Flow rate; Mathematical models; Oxides; Sand; Surface chemistry; Wastewater treatment
• ISSN: 0169-4332
• DOI: 10.1016/j.apsusc.2014.11.068

The mixture of several effluents, caused by the improper handling and management of effluents, generated multi-component wastewater containing both metals and dyes, leading to the complicated treatment process. In this study, a continuous adsorption of Pb(II) and methylene blue (MB) has been studied in single and binary solutions by using graphite oxide coated sand (GO-sand) as an adsorbent in a fixed-bed column. GO-sand was analyzed by X-ray photoelectron spectroscopy before and after analyte adsorption. Compared with sand filter, adsorption quantity and capacity for Pb(II) and MB by GO-sand filter were greatly increased. In Pb(II) and MB single solutions, the experimental parameters were investigated in detail including initial concentration, flow rate, bed depth and pH. Exhaustion time decreased with increasing initial concentration and flow rate, and increased with increasing bed depth and pH. In the Pb(II)-MB binary solution, exhaustion time significantly decreased for Pb(II) adsorption, but increased for MB adsorption. The reason was explained that the more favorable adsorption for MB onto the surface of GO-sand than that for Pb(II), which was derived from pi - pi interaction between MB and GO on sand surface in packed filter. The Yoon-Nelson model was applied at different concentration of Pb(II) and MB to predict the breakthrough curves. The experimental data were well fit with the model indicating that it was suitable for this column design.