WS2 as highly active co-catalyst for the regeneration of Fe(II) in the advanced oxidation processes

• Published in: Chemosphere (Oxford) Vol. 262; p. 128067
• Main Authors: Luo, Haopeng, Zhou, Xin, Guo, Xiaojie, Fang, Zhiyong, Chen, Quanyuan, Zhou, Juan
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 01.01.2021
• Subjects: 4-CP; Co-catalytic effect; Fe(II)/Fe(III) cycle; free radicals; humic acids; oxidation; PMS activation; WS2; PMS activation; 4-CP; WS2; Co-catalytic effect; Fe(II)/Fe(III) cycle
• ISSN: 0045-6535; 1879-1298; 1879-1298
• DOI: 10.1016/j.chemosphere.2020.128067

The greatest constraint in the advanced oxidation processes involved Fe(II)/PMS was the low utilization of Fe(II) and PMS. In the present study, the co-catalytic effect of WS2 on the Fe(II)/PMS system for the degradation of organics was investigated. In the presence of WS2, Fe(III) was reduced to Fe(II) during the reaction and resulted in improved decomposition of PMS as well as the degradation of 4-chloriphenol (4-CP). The decomposition rate of PMS and degradation efficiency of 4-CP were 10% and 25% in the Fe(II)/PMS process, while the efficiencies respectively increased to 99% and 100% in the WS2 assisted Fe(II)/PMS system. The degradation of 4-CP was completed via the free radical pathway and SO4•- played a more important role than other active species. Low concentration of inorganic ions such as Cl− and HCO3− exhibited irrelevant effect while humic acid showed significant suppression on the WS2/Fe(II)/PMS system. Additionally, characterization and recycle results implied that WS2 maintained a good stability during the co-catalytic processes. Fe(II) was regenerated effectively with the assistance of WS2 in the advanced oxidation processes involved PMS decomposition. [Display omitted] •Cyclic conversion of Fe(II)/Fe(III) was achieved by the addition of WS2.•The decomposition of PMS was remarkably enhanced in the presence of WS2.•WS2 maintained a good stability after the co-catalytic processes.•Cl−, HCO3− and humic acid showed different suppress effects on the reaction.