Facile synthesis and up-conversion properties of monodisperse rare earth fluoride nanocrystals

• Published in: Dalton transactions : an international journal of inorganic chemistry Vol. 41; no. 38; pp. 11716 - 11724
• Main Authors: Gai, Shili, Yang, Guixin, Li, Xingbo, Li, Chunxia, Dai, Yunlu, He, Fei, Yang, Piaoping
• Format: Journal Article
• Language: English
• Published: England 14.10.2012
• Subjects: Alkenes - chemistry; Colloids; Cyclohexanes - chemistry; Dimethylpolysiloxanes - chemistry; Erbium; Fluorides; Fluorides - chemistry; Metal Nanoparticles - chemistry; Metals, Rare Earth - chemistry; Morphology; Nanocrystals; Oleic Acid - chemistry; Rare earth metals; Solvents; Spectrometry, Fluorescence; Upconversion
• ISSN: 1477-9226; 1477-9234; 1477-9234
• DOI: 10.1039/c2dt30954h

Monodisperse rare earth (RE) fluoride colloidal nanocrystals (NCs) including REF(3) (RE = La, Pr, Nd), NaREF(4) (RE = Sm-Ho, Y) and Na(5)RE(9)F(32) (RE = Er, Yb, Lu) have been successfully synthesized by a facile one-step method using oleic acid as surfactant and 1-octadecene as solvent. The phase, morphology, size, and photoluminescence properties of as-synthesized NCs were well investigated by X-ray diffraction (XRD), transmission electron microscopy (TEM) and high-resolution transmission electron microscopy (HRTEM), Fourier transform infrared spectroscopy (FT-IR), and photoluminescence (PL) spectra. The results reveal that the as-synthesized NCs consist of monodisperse colloidal NCs with narrow size distribution, which can easily disperse in non-polar cyclohexane solvent. The as-prepared NCs exhibit a rich variety of morphologies and different crystal phases (hexagonal or cubic), which may be related to the inherent natures of different rare earth ions. The possible formation mechanism of NCs with diverse architectures has been presented. In addition, representative Yb/Er, Yb/Tm, or Yb/Ho co-doped NaGdF(4) and Na(5)Lu(9)F(32) NCs exhibit intensive multicolor up-conversion (UC) luminescence under a single 980 nm NIR excitation, displaying potential applications in bioimaging and therapy. Moreover, transparent and UC fluorescent NCs-polydimethylsiloxane (PDMS) composites with regular dimensions were also prepared by an in situ polymerization route.