Heavy metal boryl chemistry: complexes of cadmium, mercury and lead

Synthetic routes to the first boryl complexes of cadmium and mercury are reported via transmetallation from boryllithium; the syntheses of related group 14 systems highlight the additional factors associated with extension to more redox-active post-transition elements.

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Bibliographic Details
Published inChemical communications (Cambridge, England) Vol. 50; no. 29; pp. 3841 - 3844
Main Authors Protchenko, Andrey V, Dange, Deepak, Schwarz, Andrew D, Tang, Christina Y, Phillips, Nicholas, Mountford, Philip, Jones, Cameron, Aldridge, Simon
Format Journal Article
LanguageEnglish
Published England 01.01.2014
Subjects
Cadmium
Heavy metals
Lead (metal)
Mercury (metal)
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Summary:Synthetic routes to the first boryl complexes of cadmium and mercury are reported via transmetallation from boryllithium; the syntheses of related group 14 systems highlight the additional factors associated with extension to more redox-active post-transition elements.
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ISSN:1359-7345
1364-548X
DOI:10.1039/c4cc00697f