Effect of vanadium doping on ZnO sensing properties synthesized by spray pyrolysis

• Published in: Materials & Design Vol. 139; pp. 56 - 64
• Main Authors: El khalidi, Zahira, Comini, Elisabetta, Hartiti, Bouchaib, Moumen, Abderrahim, Munasinghe Arachchige, Hashitha M.M., Fadili, Salah, Thevenin, Philippe, Kamal, Abderrafi
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 05.02.2018; Elsevier
• Subjects: Acetone; Engineering Sciences; Gas sensors; Surface morphology; V doped ZnO; Working temperature; V doped ZnO; Working temperature; Gas sensors; Surface morphology; Acetone
• ISSN: 0264-1275; 0261-3069; 1873-4197; 0264-1275
• DOI: 10.1016/j.matdes.2017.10.074

•Vanadium dopant with 4% was added to zinc oxide (ZnO) to optimize its gas sensing properties.•The incorporation of vanadium improved the grain size with diameter below 9nm.•Working temperature under gases reduced from 350°C to 300°C due to adsorption phenomena.•Vanadium doped ZnO showed high response of 100 under 100ppm of acetone, at 450°C. [Display omitted] Semiconductor oxides with high sensing capacity remain a real challenge from long ago. Several attempts were considered to enhance the sensor's performance factors and achieve high quality requirements. In the present work, we operated a chemical sensor using intrinsic and vanadium doped zinc oxide. These samples were prepared and deposited using low cost spray pyrolysis technique. The structural data revealed good surface morphology and roughness, confirming the existence of ideal environment for oxidizing/reduction reactions. The addition of 4% vanadium minimized the grain size with a diameter lower than 9nm. The gas testing measurements showed that vanadium doped ZnO presented higher response compared to pure ZnO. V-doped ZnO confirmed an improvement of the optimal operating temperature which varies from 350°C to 300°C at 100ppm of acetone, 50ppm of ethanol and 500ppm of H2. Furthermore, V-doped ZnO showed a maximum response reaching 100 at 100ppm, for 450°C. This high response is attributed to the effect of vanadium impurities that altered ZnO structure which was confirmed by structural data.