Synthesis of lithium corrole and its use as a reagent for the preparation of cyclopentadienyl zirconium and titanium corrole complexes

The lithium corrole complex (Mes(2)(p-OMePh)corrole)Li(3)·6THF (1·6THF), prepared via deprotonation of the free-base corrole with lithium amide, acts as precursor for the preparation of cyclopentadienyl zirconium(iv) corrole (2) and pentamethylcyclopentadienyl titanium(IV) corrole (3).

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Bibliographic Details
Published inChemical communications (Cambridge, England) Vol. 48; no. 87; pp. 10766 - 10768
Main Authors Buckley, Heather L, Chomitz, Wayne A, Koszarna, Beata, Tasior, Mariusz, Gryko, Daniel T, Brothers, Penelope J, Arnold, John
Format Journal Article
LanguageEnglish
Published England 01.01.2012
Subjects
Amides
Lithium
Lithium - chemistry
Models, Molecular
Molecular Structure
Organometallic Compounds - chemical synthesis
Organometallic Compounds - chemistry
Porphyrins - chemistry
Precursors
Synthesis
Titanium
Titanium - chemistry
Zirconium
Zirconium - chemistry
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Summary:The lithium corrole complex (Mes(2)(p-OMePh)corrole)Li(3)·6THF (1·6THF), prepared via deprotonation of the free-base corrole with lithium amide, acts as precursor for the preparation of cyclopentadienyl zirconium(iv) corrole (2) and pentamethylcyclopentadienyl titanium(IV) corrole (3).
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ISSN:1359-7345
1364-548X
DOI:10.1039/c2cc35984g