Between porphyrins and phthalocyanines: 10,20-diaryl-5,15-tetrabenzodiazaporphyrins

meso-Diaryltetrabenzo(opp)diazaporphyrins are made readily available via Curtius rearrangement of azidocarbonyl derivatives of meso-aryldibenzodipyrromethenes, readily generated with or without isolation from tert-butoxycarbonyl derivatives of the same system. The new tetrapyrrolic dyes are isostruc...

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Bibliographic Details
Published inChemical communications (Cambridge, England) Vol. 50; no. 59; pp. 7953 - 7955
Main Authors Andrianov, D. S., Rybakov, V. B., Cheprakov, A. V.
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 01.01.2014
Subjects
Chemistry
Chemistry, Multidisciplinary
Derivatives
Dyes
Physical Sciences
Porphyrins
Science & Technology
TETRABENZOPORPHYRINS
ZINC-COMPLEXES
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Summary:meso-Diaryltetrabenzo(opp)diazaporphyrins are made readily available via Curtius rearrangement of azidocarbonyl derivatives of meso-aryldibenzodipyrromethenes, readily generated with or without isolation from tert-butoxycarbonyl derivatives of the same system. The new tetrapyrrolic dyes are isostructural with 5,15-diaryltetrabenzoporphyrins and resemble both phthalocyanines and tetrabenzoporphyrins to afford an interesting new system for optical applications and material research.
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ISSN:1359-7345
1364-548X
DOI:10.1039/c4cc02405b